Faculty of Engineering and Computer Science, Osnabrück University of Applied Science, Osnabrück, Germany
A3 Water Solutions GmbH, Saerbeck, Germany
Chair of Chemical and Process Engineering, Technische Universität Berlin, Berlin, Germany
Purpose Membrane filtration is recently applied to recover nutrients and dischargeable water from anaerobic sludge. The purpose of this study is to quantify nutrient separation, membrane performance, and process stability and to increase the economical applicability of the process by energetic optimization.
Methods At the site of a 2.5 MWe agricultural biogas plant, a membrane pilot plant was operated over a period of 7 months. It consisted of a screw press separator, a decanter centrifuge, an ultrafiltration unit, and a three-stage reverse osmosis unit. Mass and nutrient balances were generated by sampling and analyzing every process stream. Process performance was analyzed by monitoring separation efficiencies, membrane fux, cleaning intervals, and energy demand.
Results Solid/liquid separation resulted in separation efficiencies of 70% for total solids and 80% for phosphorus. The solid fraction contained high concentrations of organics and particle-ligated nutrients (20% TS, 8 kg t−1 Ntotal, 5.5 kg t−1 P2O5). The retentive of the reverse osmosis had high concentrations of dissolved ammonia and potassium (4 kg t−1 NH4–N and 10 kg t−1 K2O). 38% of the sludge volume was recovered as clean water.
Conclusion The membrane pilot plant successfully produced a solid N/P-fertilizer, a liquid N/K-fertilizer and clean water. The results contribute to a sound understanding and growing database for future adaption of the process chain. Hydrodynamic optimization within the pilot plant reduced the energy demand of the ultrafiltration step by 50%, which considerably contributes to the economy of the process.